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A 6/5/5/7 heterotetracyclic indole derivative alkaloid isolated from Typhonium giganteum

Abstract

Typhoniumoid A (1), a new skeleton type alkaloid which was similar to carboline, possessed a 6/5/5/7 heterotetracyclic fused coupling with an unprecedented 7,5-spirocyclic moiety was isolated from Typhonium giganteum Engl. The structure was completely elucidated by combination of diverse methods which include one and two dimensional NMR, and ECD calculations. (C) 2019 Elsevier Ltd. All rights reserved.

article Article
date_range 2020
language English
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Featured Keywords

Typhoniumoid A
Typhonium giganteum
Carboline
Heterotetracyclic system
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