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Get Free AccessThe position of the lithium in the title compound 1, which formally contains an α-sulfonyl carbanion, has been clarified by an X-ray structure analysis: In dimeric 1 the two Li atoms are each coordinated to two O atoms and two N atoms. Consistent with this finding, the CαS distance is extraordinarily short.
Gernot Boche, Michael Marsch, Klaus Harms, In Memory: G.M. Sheldrick (1942–2025) (1985). X‐Ray Structure Determination of [α‐(Phenylsulfonyl)benzyllithium‐Tetramethylethylenediamine]<sub>2</sub>: Chirality of an α‐Sulfonyl “Carbanion”. Angewandte Chemie International Edition, 24(7), pp. 573-575, DOI: 10.1002/anie.198505731.
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Type
Article
Year
1985
Authors
4
Datasets
0
Total Files
0
Language
English
Journal
Angewandte Chemie International Edition
DOI
10.1002/anie.198505731
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