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Get Free AccessOne dimensional channels are formed in the three-dimensional open-framework iron selenite [C 4 N 2 H 12 ] 0.5 [Fe 2 F 3 (SeO 3 ) 2 ] (I), which was synthesized hydrothermally from FeCl 3 ·6H 2 O, HF, and SeO 2 in the presence of the organic amine piperazine. The same inorganic framework was also obtained with the amines diethylenetetramine, 1,3-diaminopropane, and ethylenediamine. Compound I displays unusual magnetic frustration behavior that is attributed to the tetrahedral geometry.
Amitava Choudhury, Udaya Kumar D, Cnr Rao (2002). Three‐Dimensional Organically Templated Open‐Framework Transition Metal Selenites. Angewandte Chemie International Edition, 41(1), pp. 158-161, DOI: 10.1002/1521-3773(20020104)41:1<158::aid-anie158>3.0.co;2-#.
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Type
Article
Year
2002
Authors
3
Datasets
0
Total Files
0
Language
English
Journal
Angewandte Chemie International Edition
DOI
10.1002/1521-3773(20020104)41:1<158::aid-anie158>3.0.co;2-#
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