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Get Free AccessA solution-phase synthesis of monodisperse SnTe nanocrystals via the reaction of bis[bis(trimethylsilyl)amino]tin(II) with trioctylphosphine telluride in oleylamine is demonstrated. The obtained SnTe nanocrystals are single-crystalline particles with a cubic rock-salt crystal structure. The size of the SnTe nanocrystals can be precisely tuned in the range of 4.5−15 nm by tailoring the reaction temperature and stabilizer concentration. These SnTe nanocrystals exhibit size-tunable band gap energies of 0.38−0.8 eV. The narrow size-distributions allow assembling SnTe nanocrystals into 3-dimensional superlattices.
Maksym V. Kovalenko, Wolfgang Heiß, Elena V. Shevchenko, Jong‐Soo Lee, Harald Schwinghammer, Paul Alivisatos, Dmitri V. Talapin (2007). SnTe Nanocrystals: A New Example of Narrow-Gap Semiconductor Quantum Dots. , 129(37), DOI: https://doi.org/10.1021/ja074481z.
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Type
Article
Year
2007
Authors
7
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/ja074481z
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