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Get Free AccessFluorinating Pyridine Appending fluorine substituents to carbon centers is commonly used to tune small-molecule properties in pharmaceutical and agrochemical research. However, fluorinations often require the use of corrosive, hazardous reagents. Fier and Hartwig (p. 956 ) present an unusually mild and convenient protocol for fluorinating carbon sites adjacent to nitrogen in pyridines and related nitrogen-bearing arenes. The reaction entails treatment with silver difluoride and proceeds rapidly at room temperature.
Patrick S. Fier, John F Hartwig (2013). Selective C-H Fluorination of Pyridines and Diazines Inspired by a Classic Amination Reaction. , 342(6161), DOI: https://doi.org/10.1126/science.1243759.
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Type
Article
Year
2013
Authors
2
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1126/science.1243759
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