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Get Free AccessThe polymerization mechanism and key oligomer intermediates during thermal condensation of benzoguanamine (BG) are unclear. Herein, we report a mixed thermal condensation strategy using BG and pre-synthesized dimer to produce the trimer (BG)₃ with significantly enhanced yield. Comprehensive characterizations confirm its linear structure. (BG)₃ exhibits a high molar absorption coefficient, approximately double the dimer and quadruple the monomer. Crucially, it displays crystallization-induced room-temperature phosphorescence (CIRTP) with a lifetime of 514.9 µs in the crystalline state.
Peng Meng, Feng Gao, Bo Wu, Jiaqi Peng, Lei Zeng, Jingsan Xu, Daigo Miyajima, Parvej Alam, Ben Zhong Tang, Zijie Qiu (2025). Scalable Solvent-Free Synthesis of a Linear Heteroaromatic Trimer with Crystallization-Induced Room-Temperature Phosphorescence. , DOI: https://doi.org/10.26434/chemrxiv-2025-btcwx.
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Type
Preprint
Year
2025
Authors
10
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.26434/chemrxiv-2025-btcwx
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