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Get Free AccessThe phase separation of ultrathin polymer-blend films of polystyrene and polybutadiene on microcontact printed alkanethiol patterns with hydrophobic and hydrophilic end groups $(\ensuremath{-}{\mathrm{CH}}_{3}$ and -COOH) is investigated by atomic force microscopy. Simulations suggest that the phase-separation morphology can be controlled through patterns that modulate the polymer-surface interaction, and this concept is verified experimentally. Length scale pattern control is found to be limited to a scale on the order of a few micrometers.
Alamgir Karim, Jack F. Douglas, B. P. Lee, Sharon C. Glotzer, John A. Rogers, Rebecca J. Jackman, Eric J. Amis, George M M Whitesides (1998). Phase separation of ultrathin polymer-blend films on patterned substrates. , 57(6), DOI: https://doi.org/10.1103/physreve.57.r6273.
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Type
Article
Year
1998
Authors
8
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1103/physreve.57.r6273
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