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Get Free AccessThe reaction of aryl halides with secondary amines in the presence of silylamide base and tri-o-tolyphopshine palladium complexes gives arylamine products. This process provides a convenient method for performing these hetero-cross coupling reactions without the necessity for forming tin amides and disposing of tin halides. This reaction follows from a mechanistic analysis of the coupling reaction with tin amides and occurs as a result of the cleavage of palladium aryl halide dimers with secondary amines.
Janis Louie, John F Hartwig (1995). Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents. , 36(21), DOI: https://doi.org/10.1016/0040-4039(95)00605-c.
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Type
Article
Year
1995
Authors
2
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1016/0040-4039(95)00605-c
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