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Get Free AccessThe development of an enantioselective palladium-catalyzed 1,1-fluoroarylation of unactivated aminoalkenes is described. The reaction uses arylboronic acids as the arene source and Selectfluor as the fluorine source to generate benzylic fluorides in good yields with excellent enantioselectivities. This transformation, likely proceeding through an oxidative Heck mechanism, affords 1,1-difunctionalized alkene products.
Ying He, Zhen‐Yu Yang, Richard T. Thornbury, Dean Toste (2015). Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes. , 137(38), DOI: https://doi.org/10.1021/jacs.5b07795.
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Type
Article
Year
2015
Authors
4
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/jacs.5b07795
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