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Get Free AccessThe ferromagnetic structure of ${\mathrm{BiMnO}}_{3},$ ${T}_{c}=105 \mathrm{K},$ has been determined from powder neutron-diffraction data collected at 20 K on a sample synthesized at high pressures using a cubic anvil press. ${\mathrm{BiMnO}}_{3}$ is a distorted perovskite that crystallizes in the monoclinic space group $C2$ with unit-cell parameters $a=9.5317(7) \AA{},$ $b=5.6047(4) \AA{},$ $c=9.8492(7) \AA{},$ and $\ss{}=110.60(1)\ifmmode^\circ\else\textdegree\fi{}$ $(Rp=6.78%,$ $wRp=8.53%,$ reduced ${\ensuremath{\chi}}^{2}=1.107).$ Data analysis reveals a collinear ferromagnetic structure with the spin direction along [010] and a magnetic moment of $3.2\ensuremath{\mu}B.$ There is no crystallographic phase transition on cooling the polar room-temperature structure to 20 K, lending support to the belief that ferromagnetism and ferroelectricity coexist in ${\mathrm{BiMnO}}_{3}.$ Careful examination of the six unique Mn-O-Mn superexchange pathways between the three crystallographically independent ${\mathrm{Mn}}^{3+}$ sites shows that four are ferromagnetic and two are antiferromagnetic, thereby confirming that the ferromagnetism of ${\mathrm{BiMnO}}_{3}$ stems directly from orbital ordering.
António M. dos Santos, Anthony K. Cheetham, Toshiyuki Atou, Yasuhiko Syono, Yasuo Yamaguchi, Kenji Ohoyama, Hiroshi Chiba, Cnr Rao (2002). Orbital ordering as the determinant for ferromagnetism in biferroic<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">BiMnO</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>. Physical review. B, Condensed matter, 66(6), DOI: 10.1103/physrevb.66.064425.
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Type
Article
Year
2002
Authors
8
Datasets
0
Total Files
0
Language
English
Journal
Physical review. B, Condensed matter
DOI
10.1103/physrevb.66.064425
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