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  5. Orbital ordering as the determinant for ferromagnetism in biferroic<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">BiMnO</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>

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Article
English
2002

Orbital ordering as the determinant for ferromagnetism in biferroic<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">BiMnO</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>

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English
2002
Physical review. B, Condensed matter
Vol 66 (6)
DOI: 10.1103/physrevb.66.064425

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Cnr Rao
Cnr Rao

Jawaharlal Nehru Centre for Advanced Scientific Research

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António M. dos Santos
Anthony K. Cheetham
Toshiyuki Atou
+5 more

Abstract

The ferromagnetic structure of ${\mathrm{BiMnO}}_{3},$ ${T}_{c}=105 \mathrm{K},$ has been determined from powder neutron-diffraction data collected at 20 K on a sample synthesized at high pressures using a cubic anvil press. ${\mathrm{BiMnO}}_{3}$ is a distorted perovskite that crystallizes in the monoclinic space group $C2$ with unit-cell parameters $a=9.5317(7) \AA{},$ $b=5.6047(4) \AA{},$ $c=9.8492(7) \AA{},$ and $\ss{}=110.60(1)\ifmmode^\circ\else\textdegree\fi{}$ $(Rp=6.78%,$ $wRp=8.53%,$ reduced ${\ensuremath{\chi}}^{2}=1.107).$ Data analysis reveals a collinear ferromagnetic structure with the spin direction along [010] and a magnetic moment of $3.2\ensuremath{\mu}B.$ There is no crystallographic phase transition on cooling the polar room-temperature structure to 20 K, lending support to the belief that ferromagnetism and ferroelectricity coexist in ${\mathrm{BiMnO}}_{3}.$ Careful examination of the six unique Mn-O-Mn superexchange pathways between the three crystallographically independent ${\mathrm{Mn}}^{3+}$ sites shows that four are ferromagnetic and two are antiferromagnetic, thereby confirming that the ferromagnetism of ${\mathrm{BiMnO}}_{3}$ stems directly from orbital ordering.

How to cite this publication

António M. dos Santos, Anthony K. Cheetham, Toshiyuki Atou, Yasuhiko Syono, Yasuo Yamaguchi, Kenji Ohoyama, Hiroshi Chiba, Cnr Rao (2002). Orbital ordering as the determinant for ferromagnetism in biferroic<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">BiMnO</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>. Physical review. B, Condensed matter, 66(6), DOI: 10.1103/physrevb.66.064425.

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Publication Details

Type

Article

Year

2002

Authors

8

Datasets

0

Total Files

0

Language

English

Journal

Physical review. B, Condensed matter

DOI

10.1103/physrevb.66.064425

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