On the origin of tropospheric ozone and NO_x over the tropical South Pacific

The budgets of ozone and nitrogen oxides (NO x = NO + NO 2 ) in the tropical South Pacific troposphere are analyzed by photochemical point modeling of aircraft observations at 0–12 km altitude from the Pacific Exploratory Mission‐Tropics A campaign flown in September‐October 1996. The model reproduces the observed NO 2 /NO concentration ratio to within 30% and has similar success in simulating observed concentrations of peroxides ( H 2 O 2 , CH 3 OOH), lending confidence in its use to investigate ozone chemistry. It is found that chemical production of ozone balances only half of chemical loss in the tropospheric column over the tropical South Pacific. The net loss is 1.8 × 10 11 molecules cm −2 s −1 . The missing source of ozone is matched by westerly transport of continental pollution into the region. Independent analysis of the regional ozone budget with a global three‐dimensional model corroborates the results from the point model and reveals the importance of biomass burning emissions in South America and Africa for the ozone budget over the tropical South Pacific. In this model, biomass burning increases average ozone concentrations by 7–8 ppbv throughout the troposphere. The NO x responsible for ozone production within the South Pacific troposphere below 4 km can be largely explained by decomposition of peroxyacetylnitrate ( PAN) transported into the region with biomass burning pollution at higher altitudes.