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Get Free AccessThe reaction of H2L1 and H2L2 with divalent metal ions leads to octanuclear bis(triple-helical) metal(II) complexes of the general composition [Zn8O2L26] (3) and [M8O2L16] (4: M = Cd2+; 5: M = Mn2+). NMR studies of the diamagnetic cadmium complex 4c show six equivalent ligands. Unambiguous characterisation of 5b was achieved by X-ray crystallographic analysis.
Rolf W. Saalfrank, Norbert Löw, Stefan Trümmer, In Memory: G.M. Sheldrick (1942–2025), M. Teichert, Dietmar Stalke (1998). Octanuclear Bis(triple-helical) Metal(II) Complexes. European Journal of Inorganic Chemistry, 1998(5), pp. 559-563, DOI: 10.1002/(sici)1099-0682(199805)1998:5<559::aid-ejic559>3.0.co;2-m.
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Type
Article
Year
1998
Authors
6
Datasets
0
Total Files
0
Language
English
Journal
European Journal of Inorganic Chemistry
DOI
10.1002/(sici)1099-0682(199805)1998:5<559::aid-ejic559>3.0.co;2-m
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