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  5. Nickel‐Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts

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Article
en
2015

Nickel‐Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts

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en
2015
Vol 54 (12)
Vol. 54
DOI: 10.1002/anie.201500404

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John F Hartwig
John F Hartwig

University of California, Berkeley

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Rebecca A. Green
John F Hartwig

Abstract

Abstract The nickel‐catalyzed amination of aryl chlorides to form primary arylamines occurs with ammonia or ammonium sulfate and a well‐defined single‐component nickel(0) precatalyst containing a Josiphos ligand and an η 2 ‐bound benzonitrile ligand. This system also catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts.

How to cite this publication

Rebecca A. Green, John F Hartwig (2015). Nickel‐Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts. , 54(12), DOI: https://doi.org/10.1002/anie.201500404.

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Publication Details

Type

Article

Year

2015

Authors

2

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0

Total Files

0

Language

en

DOI

https://doi.org/10.1002/anie.201500404

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