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  5. Metal‐Organic Frameworks with Rod Yttrium Secondary Building Units

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Article
en
2023

Metal‐Organic Frameworks with Rod Yttrium Secondary Building Units

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en
2023
Vol 63 (7-8)
Vol. 63
DOI: 10.1002/ijch.202300017

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Omar M Yaghi
Omar M Yaghi

University of California, Berkeley

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Zhiling Zheng
Zichao Rong
Oscar Iu‐Fan Chen
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Abstract

Abstract We report a new hydroxamate‐based yttrium MOF, named MOF‐419 [Y(HCOO)(BDH)], with rod‐SBUs. The compound was synthesized employing chelating construction of benzene‐1,4‐hydroxamate (BDH 2− ) linkers, and the use of formic acid as the modulator was found to be crucial for the formation of rod‐shaped SBUs. MOF‐419 shows permanent porosity and has a BET surface area of 1130 m 2 /g. Its hydrophobic pore environment and gas sorption properties were demonstrated through the combination of single crystal X‐ray diffraction and nitrogen, carbon dioxide, and water sorption experiments. We envision that these results will aid the study and understanding of rod MOFs with chelating linkages.

How to cite this publication

Zhiling Zheng, Zichao Rong, Oscar Iu‐Fan Chen, Omar M Yaghi (2023). Metal‐Organic Frameworks with Rod Yttrium Secondary Building Units. , 63(7-8), DOI: https://doi.org/10.1002/ijch.202300017.

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Publication Details

Type

Article

Year

2023

Authors

4

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0

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Language

en

DOI

https://doi.org/10.1002/ijch.202300017

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