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Get Free AccessMonodisperse sub-10 nm Rh nanocubes were synthesized with high selectivity (>85%) by a seedless polyol method. The {100} faces of the Rh NCs were effectively stabilized by chemically adsorbed Br- ions from trimethyl(tetradecyl)ammonium bromide (TTAB). This simple one-step polyol route can be readily applied to the preparation of Pt and Pd nanocubes. Moreover, the organic molecules of PVP and TTAB that encapsulated the Rh nanocubes did not prevent catalytic activity for pyrrole hydrogenation and CO oxidation.
Ya‐Wen Zhang, Michael Graß, John N. Kuhn, Tao Feng, Susan E. Habas, Wenyu Huang, Peidong Yang, Gabor Somorjai (2008). Highly Selective Synthesis of Catalytically Active Monodisperse Rhodium Nanocubes. , 130(18), DOI: https://doi.org/10.1021/ja801210s.
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Type
Article
Year
2008
Authors
8
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/ja801210s
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