Growth of Sharp Tips on Gold Nanowires Leads to Increased Surface-Enhanced Raman Scattering Activity

We report the formation of gold nanoparticles with a novel and useful morphology, comprising nanowires fully covered with sharp tips (thorned nanowires). The synthesis is based on a seeded-growth approach based the rapid overgrowth of ultrathin gold wires in N,N-dimethylformamide, in the presence of poly(vinylpyrrolidone). The process allows a fine control over the thickness of the final wires, as well as the tunability of the number and sharpness of the thorns. These new plasmonic nanostructures display extremely strong optical enhancing properties and can be readily used as platforms for SERS and for integration in ultrasensitive optical devices.