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  5. Ester-Linked Crystalline Covalent Organic Frameworks

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Article
en
2020

Ester-Linked Crystalline Covalent Organic Frameworks

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en
2020
Vol 142 (34)
Vol. 142
DOI: 10.1021/jacs.0c07015

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Omar M Yaghi
Omar M Yaghi

University of California, Berkeley

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Chenfei Zhao
Hao Lyu
Zhe Ji
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Abstract

Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D structures in kgm (COF-119) and hcb (COF-120, 121, 122) topologies with surface areas of up to 2092 m2/g. Notably, crystalline COF-122 comprises edges spanning over 10 phenylene units, an aspect that had only been achieved in metal-organic frameworks. This work expands the scope of reticular chemistry to include, for the first time, crystalline ester-linked COFs related to common polyesters.

How to cite this publication

Chenfei Zhao, Hao Lyu, Zhe Ji, Chenhui Zhu, Omar M Yaghi (2020). Ester-Linked Crystalline Covalent Organic Frameworks. , 142(34), DOI: https://doi.org/10.1021/jacs.0c07015.

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Publication Details

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Article

Year

2020

Authors

5

Datasets

0

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0

Language

en

DOI

https://doi.org/10.1021/jacs.0c07015

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