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Get Free AccessStereoselective synthesis of two fluorine-bearing drug-like scaffolds, dihydroquinazolone and benzooxazinone, has been accomplished through asymmetric fluorocyclization reactions initiated by the fluorination process. The reaction employs double axially chiral anionic phase-transfer catalysts to achieve high diastereo- and enantioselectivities, and a wide range of fluorine-containing dihydroquinazolones were obtained (>20:1 dr, up to 98% ee).
Kenichi Hiramatsu, Takashi Honjo, Vivek Rauniyar, Dean Toste (2015). Enantioselective Synthesis of Fluoro–Dihydroquinazolones and −Benzooxazinones by Fluorination-Initiated Asymmetric Cyclization Reactions. , 6(1), DOI: https://doi.org/10.1021/acscatal.5b02182.
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Type
Article
Year
2015
Authors
4
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/acscatal.5b02182
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