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Get Free AccessIn benzene solution, C60 and C70 interact weakly in the ground state with amines having favourable oxidation potentials. Picosecond time-resolved absorption measurements show that on photoexcilation, the weak complexes undergo charge separation to produce ion pairs which in turn undergo fast geminate recombination either to produce the triplet state of the fullerenes or give back the ground slate of the complex, depending on the oxidation potential of the amine. Free-ion yield is generally negligible.
Dipak K. Palit, Hirendra N. Ghosh, Haridas Pal, A. V. Sapre, J.P. Mittal, Ram Seshadri, Cnr Rao (1992). Dynamics of charge transfer in the excited amine complexes of the fullerenes C60 and C70.. Chemical Physics Letters, 198(1-2), pp. 113-117, DOI: 10.1016/0009-2614(92)90057-t.
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Type
Article
Year
1992
Authors
7
Datasets
0
Total Files
0
Language
English
Journal
Chemical Physics Letters
DOI
10.1016/0009-2614(92)90057-t
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