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Get Free AccessWe report a one-pot, direct C-H functionalization reaction of alkenes mediated by [CpCo(NO)(2)]. All intermediates in the proposed reaction sequence have been characterized. A variety of Michael acceptors can be utilized with the one-pot procedure to give the desired cyclic tetra-alkyl-substituted, γ,δ-unsaturated compounds in good yields. We also provide a preliminary result for catalytic turnover in both base and [CpCo(NO)(2)].
Chen Zhao, Dean Toste, Robert G. Bergman (2011). Direct Michael Addition of Alkenes via a Cobalt-Dinitrosyl Mediated Vinylic C–H Functionalization Reaction. , 133(28), DOI: https://doi.org/10.1021/ja204564z.
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Type
Article
Year
2011
Authors
3
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/ja204564z
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