Defect Passivation of 2D Semiconductors by Fixating Chemisorbed Oxygen Molecules via <i>h</i>‐BN Encapsulations

Hexagonal boron nitride (h-BN) is a key ingredient for various 2D van der Waals heterostructure devices, but the exact role of h-BN encapsulation in relation to the internal defects of 2D semiconductors remains unclear. Here, it is reported that h-BN encapsulation greatly removes the defect-related gap states by stabilizing the chemisorbed oxygen molecules onto the defects of monolayer WS₂ crystals. Electron energy loss spectroscopy (EELS) combined with theoretical analysis clearly confirms that the oxygen molecules are chemisorbed onto the defects of WS₂ crystals and are fixated by h-BN encapsulation, with excluding a possibility of oxygen molecules trapped in bubbles or wrinkles formed at the interface between WS₂ and h-BN. Optical spectroscopic studies show that h-BN encapsulation prevents the desorption of oxygen molecules over various excitation and ambient conditions, resulting in a greatly lowered and stabilized free electron density in monolayer WS₂ crystals. This suppresses the exciton annihilation processes by two orders of magnitude compared to that of bare WS₂. Furthermore, the valley polarization becomes robust against the various excitation and ambient conditions in the h-BN encapsulated WS₂ crystals.