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  5. Crystalline Polyphenylene Covalent Organic Frameworks

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Preprint
en
2023

Crystalline Polyphenylene Covalent Organic Frameworks

0 Datasets

0 Files

en
2023
DOI: 10.26434/chemrxiv-2023-f8bl7

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Omar M Yaghi
Omar M Yaghi

University of California, Berkeley

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Xing Han
Zihui Zhou
Kaiyu Wang
+4 more

Abstract

The synthesis of crystalline polyphenylene covalent organic frameworks (COFs) was accomplished by linking fluorinated tris(4-acetylphenyl)benzene building units using aldol cyclotrimerization. The structures of two COFs, reported here, were confirmed by powder X-ray diffraction techniques, Fourier-transform infrared, and solid-state 13C CP/MAS NMR spectroscopy. The results showed that the COFs were porous and chemically stable in corrosive, harsh environments for at least 1 week. Accordingly, post-synthetically modified derivatives of these COFs using primary amines showed CO2 uptake from air and flue gas.

How to cite this publication

Xing Han, Zihui Zhou, Kaiyu Wang, Zhiling Zheng, Silvio Neumann, Tianqiong Ma, Omar M Yaghi (2023). Crystalline Polyphenylene Covalent Organic Frameworks. , DOI: https://doi.org/10.26434/chemrxiv-2023-f8bl7.

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Publication Details

Type

Preprint

Year

2023

Authors

7

Datasets

0

Total Files

0

Language

en

DOI

https://doi.org/10.26434/chemrxiv-2023-f8bl7

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