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Get Free AccessInteraction of nanoparticles of metals such as Ag, Au, Pt and Pd with graphene has been examined by employing Raman spectroscopy and first-principles calculations. There is a significant shift of the G-band as well as of the other bands, in addition to variation in the relative intensities of D- and 2D-bands when the metal nanoparticles are deposited on graphene. The shifts in the G- and D-bands show meaningful trends with the ionization energies of the metals as well as the charge-transfer energies. Results from the calculations underscore the importance of charge-transfer between the metal particles and graphene.
K. S. Subrahmanyam, Arun K. Manna, Swapan K. Pati, Cnr Rao (2010). A study of graphene decorated with metal nanoparticles. Chemical Physics Letters, 497(1-3), pp. 70-75, DOI: 10.1016/j.cplett.2010.07.091.
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Type
Article
Year
2010
Authors
4
Datasets
0
Total Files
0
Language
English
Journal
Chemical Physics Letters
DOI
10.1016/j.cplett.2010.07.091
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