A hybrid composite of Polypyrole/carboxymethyl cellulose/MWCNT fiber with antimicrobial properties and Sb3+ determination on a glassy carbon electrode

In order to prepare fiber-type nanohybrid composites for electrochemical and antimicrobial applications, polypyrrole was combined with carboxymethylcellulose and multiwalled carbon nanotubes (PPy/CMC/MWCNTS). These composite materials were synthesized using ultrasonication and in situ polymerization. By using analytical methods, the structure and morphology of the synthesized nanohybrid composite material were confirmed. Slurry of fiber-type PPY/CMC/MWCNT composites synthesized in ethanol was deposited as a thin-uniform layer with conductive nafion (5% ethanolic solution of nafion) binder. Based on electrochemical measurements in a phosphate buffer medium, Sb3+ ions have linear responses between 0.1 nM and 0.01 mM, which is known as linear dynamic range (LDR). A sensor’s sensitivity (22.4304 µAµM−1cm−2) is calculated using the LDR slope by considering the GCE surface area (0.0316 cm2). A signal-to-noise ratio of 3 is used to estimate the lower limit of detection which is equal to 96.82 ± 4.84 pM. Moreover, the antibacterial activity of the obtained polypyrrole/carboxymethylcellulose/MWCNT composite has also been evaluated “against Gram-positive bacteria B. subtilis along with S. aureus, as well as Gram-negative bacteria, P. aeruginosa along with Escherichia coli by utilizing” autoclave of agar media. In electrochemical analysis, the proposed Sb3+ cationic sensor exhibits appreciable reproducibility, response time, stability, and outstanding outcome in analysis of real samples. In the field of metal ion sensor, this reliable method might be prospective in the recent future.