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Get Free AccessAn intramolecular 1,2(α)-H migration in a saturated ruthenium stannylene complex, to form a ruthenostannylene complex, involves a reversal of the role for a coordinated stannylene ligand, from that of an electron donor to an acceptor in the transition state. This change in the bonding properties for a stannylene group, with a simple molecular motion, lifts the usual requirement for generation of an unsaturated metal center in migration chemistry.
Hsueh‐Ju Liu, Julie Guihaumé, Thomas Davin, Christophe Raynaud, Odile Eisenstein, T Don Tilley (2014). 1,2-Hydrogen Migration to a Saturated Ruthenium Complex via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannylene Conversion. , 136(40), DOI: https://doi.org/10.1021/ja507799e.
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Type
Article
Year
2014
Authors
6
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/ja507799e
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