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Get Free AccessThe synthesis of a novel supramolecular tetrahedral assembly of K12Ga4L6 stoichiometry is reported. The newly designed chiral ligand exhibits high diastereoselective control during cluster formation, leading exclusively to a single diastereomer of the desired host. This new assembly also exhibits high stability toward oxidation or a low pH environment and is a more robust and efficient catalyst for asymmetric organic transformations of neutral substrates.
Chen Zhao, Qing‐Fu Sun, William Hart‐Cooper, Antonio G. DiPasquale, Dean Toste, Robert G. Bergman, Kenneth N. Raymond (2013). Chiral Amide Directed Assembly of a Diastereo- and Enantiopure Supramolecular Host and its Application to Enantioselective Catalysis of Neutral Substrates. , 135(50), DOI: https://doi.org/10.1021/ja411631v.
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Type
Article
Year
2013
Authors
7
Datasets
0
Total Files
0
Language
en
DOI
https://doi.org/10.1021/ja411631v
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